If you're a fan of gangster movies and you haven't seen 'Layer Cake' then you oughta be ashamed of yourself. This 2004 flick really packs a punch. Great directing by Matthew Vaughn (who also directed Kick-Ass) and awesome acting by James Bond himself.
There is a Macallan sighting at the 1:00:50 mark which you can watch below. Daniel Craig (whose character doesn't have a name) needs some help coming to terms with the fact that he just committed his first murder. He decides to pulverize some recreational pharmaceuticals and washes 'em down with a bottle of Macallan. What a waste of perfectly good scotch.